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Peter Kazarinoff
Graduate student, Materials Science &
Engineering, UW
Energy Levels and Charge Carrier
Mobility in Carboxylate Functionalized Polythiophenes
Organic semi-conducting polymers have been the
subject of intense study during the last couple of years. These
materials are alternatives for conventional silicon based semiconductors
in low cost, easy to manufacture electronic devices such as thin film
transistors and solar cells. Three semi-conducting polythiophene based
polymers have been synthesized with electron withdrawing carboxylate
substituents. They provide better air stability, compared to other
semi-conducting polymers, due to a decreased HOMO (highest occupied
molecular orbital) by 0.5eV. These polymers still exhibit high charge
carrier mobility averaging 0.01 cm2/Vs in thin-film
transistors fabricated entirely in air.
Jason Zhou
Senior, Materials Science and Engineering, UW
Study of Rigid Natural Fibers-Lessons for New
Composites
Spicule fibers of the siliceous sponge
Euplectella aspergillum were
studied under torsional loading to determine the mechanical response of
this concentrically-ringed structure. Laser confocal scanning microscopy
and scanning electron microscopy have clarified the damage mechanisms in
these natural rigid composite systems. The results have confirmed the
controlling roles of thin protein layers, and the complex architecture
of such sponges in structural toughening. It is expected that this work
will lead to new design composite configurations for normally brittle
materials, such as undersea optical cables.
Conor D. Keenan
Senior, Materials Science and Engineering, UW
Using an Instrumented Rapid Adhesion Test (I-RAT) to Obtain a
Comparative Measure of Bond Strength
The
Rapid Adhesion Test (RAT) originated as a test method that was modified
from a metal-to-metal peel test.
It is used to quickly and inexpensively assess the mode of failure of a
composite bond. Initially
designed to produce a qualitative measure of the failure mode
representing bond quality, the test can be performed with 90% less cost
and flow time as compared to the industry standard of composite bond
analysis by the Double Cantilever Beam (DCB) test.
In order to obtain more quantitative data from the RAT test
method the Instrumented Rapid Adhesion Test (i-Rat) was developed by the
Flinn group at the University of Washington.
This modified test method incorporates the use of a Climbing Drum
Peel (CDP) fixture with bonded samples that were originally intended for
manual RAT testing. This
innovative modification to the RAT method allows us to produce a
comparative measure of bond strength using the peel torque data obtained
during testing of the bonded composite.
Different composite/adhesive/peel ply combinations in a composite
bond can therefore be ranked according to their bond strength in a very
quick and inexpensive method to help determine the best choice for a
certain application
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